Running Kiln
Kiln takes a folder to open as its argument, resolved against your shell's working directory:
Kiln . # open the repo you're standing in
Kiln ../sibling # open a neighbour
Kiln ~/code/proj # an absolute path
With no argument it restores the last session.
You can also launch Kiln like any other Mac app, from Spotlight, Launchpad, or the Dock, then open a folder from inside. The Kiln command is there for when you're already in a terminal and want to open the folder you're standing in.